Crystal structure of bis-(quinolin-1-ium) tetra-chlorido-ferrate(III) chloride.
作者信息
Boudjarda Azzedine, Bouchouit Karim, Arroudj Samiha, Bouacida Sofiane, Merazig Hocine
机构信息
Faculté des Sciences Exactes et Informatique, Département de Chimie, Université de Jijel, 18000 Jijel, Algeria.
Laboratoire des Structures, Propriétés et Interactions InterAtomiques, Université de Khenchela, 40000 Khenchela, Algeria.
出版信息
Acta Crystallogr E Crystallogr Commun. 2015 Dec 31;71(Pt 12):m273-4. doi: 10.1107/S2056989015024548. eCollection 2015 Dec 1.
The asymmetric unit of the title hybrid compound, (C9H8N)[FeCl4]Cl, comprises a tetra-hedral tetra-chlorido-ferrate(III) anion, FeCl4, a Cl(-) anion and two quinolinium cations. There are N-H⋯Cl hydrogen-bonding inter-actions between the protonated N atoms of the quinolinium cations and the chloride anion, which together with π-π stacking between adjacent quinolinium rings [centroid-to-centroid distances between C6 and C5N rings in adjacent stacked quinolinium cations of 3.609 (2) and 3.802 (2) Å] serve to hold the structure together.
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