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聚[[二水合-四-双-(μ(2)-苯-1,4-二腈-κN:N')铁(II)]双-[四氯合铁(III)]]硝基甲烷四溶剂合物

Poly[[diaqua-tetra-kis-(μ(2)-benzene-1,4-di-carbonitrile-κN:N')iron(II)] bis-[tetra-chlorido-ferrate(III)] nitro-methane tetra-solvate].

作者信息

Prommon Pimonrat, Promseenong Pinyada, Chainok Kittipong

机构信息

Department of Chemistry, Faculty of Science, Naresuan University, Muang Phitsanulok 65000, Thailand.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):m211-2. doi: 10.1107/S1600536812002486. Epub 2012 Jan 31.

DOI:10.1107/S1600536812002486
PMID:22346875
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3274928/
Abstract

In the title compound, {[Fe(II)(C(8)H(4)N(2))(2)(H(2)O)(2)]Fe(III)Cl(4)·4CH(3)NO(2)}(n), the Fe(II) and Fe(III) ions are hexa- and tetra-coordinated, respectively. Each unique benzene-1,4-dicarbonitrile mol-ecule lies across a crystallographic inversion centre and bridges two Fe(II) ions (each situated on an inversion centre), generating two-dimensional (4,4) square grid layers. The tetra-chloridoferrate(III) anions and nitro-methane solvent mol-ecules lie between the square grid layers and are further link to the adjacent layers into a three-dimensional supra-molecular structure through O-H⋯Cl and O-H⋯O hydrogen bonds.

摘要

在标题化合物{[Fe(II)(C₈H₄N₂)₂(H₂O)₂][Fe(III)Cl₄]₂·4CH₃NO₂}ₙ中，Fe(II)和Fe(III)离子分别为六配位和四配位。每个独特的苯-1,4-二甲腈分子位于一个晶体学倒转中心上，并桥连两个Fe(II)离子（每个位于一个倒转中心上），生成二维(4,4)方形网格层。四氯合铁(III)阴离子和硝基甲烷溶剂分子位于方形网格层之间，并通过O-H⋯Cl和O-H⋯O氢键进一步连接相邻层形成三维超分子结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/44e9/3274928/af273e488495/e-68-0m211-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/44e9/3274928/36bda0e58932/e-68-0m211-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/44e9/3274928/af273e488495/e-68-0m211-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/44e9/3274928/36bda0e58932/e-68-0m211-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/44e9/3274928/af273e488495/e-68-0m211-fig2.jpg

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