四氯合铁（III）酸4-（二甲氨基）吡啶鎓
4-(Dimethyl-amino)-pyridinium tetra-chloridoferrate(III).
作者信息
Khadri Amina, Bouchene Rafika, Bouacida Sofiane, Merazig Hocine, Roisnel Thierry
机构信息
Laboratoire de Chimie Appliquée et Technologie des Matériaux LCATM, Université Oum El Bouaghi, Algeria ; Département Sciences de la Matière, Faculté des Sciences Exactes et Sciences de la Nature et de la Vie, Université Oum El Bouaghi, Algeria.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2013 Mar 9;69(Pt 4):m190. doi: 10.1107/S160053681300603X. Print 2013 Apr 1.
The title salt, (C7H11N2)[FeCl4], consists of one essentially planar (the r.m.s. deviation for all non-H atoms being 0.004 Å) 4-(dimethyl-amino)-pyridinium cation and a tetra-hedral tetra-chloridoferrate(III) anion. The cations and anions are arranged in layers parallel to (010). Besides electrostatic inter-actions, the crystal packing features N-H⋯Cl and C-H⋯Cl hydrogen bonds between cations and anions, forming a three-dimensional network.
标题盐（C₇H₁₁N₂）[FeCl₄]由一个基本呈平面状的（所有非H原子的均方根偏差为0.004 Å）4-（二甲基氨基）吡啶鎓阳离子和一个四面体四氯合铁（III）阴离子组成。阳离子和阴离子平行于（010）排列成层。除了静电相互作用外，晶体堆积的特征是阳离子和阴离子之间存在N-H⋯Cl和C-H⋯Cl氢键，形成三维网络。
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