钯催化2-烯丙基苯酚区域选择性氢酯化反应合成七元内酯，无需外部一氧化碳气体。
Pd-Catalyzed regioselective hydroesterification of 2-allylphenols to seven-membered lactones without external CO gas.
作者信息
Chang Wenju, Li Jingfu, Ren Wenlong, Shi Yian
机构信息
State Key Laboratory of Coordination Chemistry, Collaborative Innovation Center of Chemistry for Life Sciences, Center for Multimolecular Organic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China.
出版信息
Org Biomol Chem. 2016 Mar 21;14(11):3047-52. doi: 10.1039/c5ob02663f. Epub 2016 Feb 19.
PMID:26891779
Abstract
Effective Pd-catalyzed regioselective hydroesterification of 2-allylphenols with phenyl formate is described. A variety of seven-membered lactones can be obtained in good yields under mild conditions without the use of toxic CO gas.
摘要
描述了钯催化2-烯丙基苯酚与甲酸苯酯的有效区域选择性氢酯化反应。在温和条件下，无需使用有毒的一氧化碳气体，即可高产率地获得多种七元内酯。
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