Li Qi, Chen Xijuan, Zhuang Jie, Chen Xin
Key Laboratory of Pollution Ecology and Environmental Engineering, Institute of Applied Ecology, Chinese Academy of Sciences, Shenyang, 110016, China.
University of Chinese Academy of Sciences, Beijing, 100049, China.
Environ Sci Pollut Res Int. 2016 Jun;23(12):11533-48. doi: 10.1007/s11356-016-6255-7. Epub 2016 Feb 24.
Organic pollutants in soils might threaten the environmental and human health. Manufactured nanoparticles are capable to reduce this risk efficiently due to their relatively large capacity of sorption and degradation of organic pollutants. Stability, mobility, and reactivity of nanoparticles are prerequisites for their efficacy in soil remediation. On the basis of a brief introduction of these issues, this review provides a comprehensive summary of the application and effectiveness of various types of manufactured nanoparticles for removing organic pollutants from soil. The main categories of nanoparticles include iron (oxides), titanium dioxide, carbonaceous, palladium, and amphiphilic polymeric nanoparticles. Their advantages (e.g., unique properties and high sorption capacity) and disadvantages (e.g., high cost and low recovery) for soil remediation are discussed with respect to the characteristics of organic pollutants. The factors that influence the decontamination effects, such as properties, surfactants, solution chemistry, and soil organic matter, are addressed.
土壤中的有机污染物可能会威胁环境和人类健康。人造纳米颗粒由于其对有机污染物相对较大的吸附和降解能力,能够有效降低这种风险。纳米颗粒的稳定性、迁移性和反应活性是其在土壤修复中发挥功效的前提条件。在简要介绍这些问题的基础上,本综述全面总结了各类人造纳米颗粒在去除土壤中有机污染物方面的应用及效果。纳米颗粒的主要类别包括铁(氧化物)、二氧化钛、碳质、钯和两亲性聚合物纳米颗粒。针对有机污染物的特性,讨论了它们在土壤修复中的优点(如独特性能和高吸附容量)和缺点(如成本高和回收率低)。还探讨了影响去污效果的因素,如性质、表面活性剂、溶液化学和土壤有机质。