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[大港工业区表层土壤重金属污染及其生态风险评价]

[Heavy Metals Pollution in Topsoil from Dagang Industry Area and Its Ecological Risk Assessment].

作者信息

Zhang Qian, Chen Zong-juan, Peng Chang-sheng, Li Fa-sheng, Gu Qing-bao

出版信息

Huan Jing Ke Xue. 2015 Nov;36(11):4232-40.

Abstract

Based on previous studies and field investigation of Dagang industry area in Tianjin, a total of 128 topsoil samples were collected, and contents of 10 heavy metals (As, Cd, Cr, Co, Cu, Pb, Ni, V, Zn and Hg) were determined. The geoaccumulation index and geostatistics were applied to examine the degree of contamination and spatial distribution of heavy metals in topsoil. The assessment on ecological risk of heavy metals was carried out using Hakanson's method, and the main resources of the heavy metals were analyzed as well. It was found that As, Cd and Co had the highest proportions exceeding Tianjin background value, which were 100%, 97.66% and 96.88%, respectively; the heavy-metal content increased to some extent comparing with that in 2004, and the pollutions of As and Cd were the worst, and other metals were at moderate pollution level or below. The ecological risks of heavy metals were different in topsoil with different land use types, the farmland soil in the southwest as well as soils adjacent to the industrial land were at relatively high potential ecological risk level, and the integrated ecological risk index reached up to 1 437.37. Analysis of correlation and principal component showed that traffic and transportation as well as agricultural activities might be the main resources of heavy metals in the area, besides, the industrial activities in the region might also affect the accumulation of heavy metals.

摘要

基于以往研究及对天津大港工业区的实地调查,共采集了128份表层土壤样本,测定了10种重金属(砷、镉、铬、钴、铜、铅、镍、钒、锌和汞)的含量。应用地累积指数和地统计学方法,研究表层土壤中重金属的污染程度和空间分布。采用哈坎松方法对重金属的生态风险进行评估,并分析了重金属的主要来源。结果表明,砷、镉和钴超过天津背景值的比例最高,分别为100%、97.66%和96.88%;与2004年相比,重金属含量有所增加,砷和镉的污染最为严重,其他金属处于中度污染水平或以下。不同土地利用类型的表层土壤中重金属的生态风险不同,西南部的农田土壤以及与工业用地相邻的土壤具有较高的潜在生态风险水平,综合生态风险指数高达1437.37。相关性分析和主成分分析表明,交通、农业活动可能是该地区重金属的主要来源,此外,该地区的工业活动也可能影响重金属的积累。

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