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[中国东部山东省典型工业城市土壤中重金属的来源、空间分布及生态风险评估]

[Assessment of sources, spatial distribution and ecological risk of heavy metals in soils in a typical industry-based city of Shandong Province, Eastern China].

作者信息

Dai Bin, Lü Jian-Shu, Zhan Jin-Cheng, Zhang Zu-Lu, Liu Yang, Zhou Ru-Jia

出版信息

Huan Jing Ke Xue. 2015 Feb;36(2):507-15.

Abstract

A total of 106 samples were collected from surface soils in Gangcheng District, Laiwu city (a Typical industry-based city of Shandong Province, Eastern China), and the contents of 9 heavy metals including As, Cd, Co, Cr, Cu, Hg, Ni, Pb and Zn were determined. Multivariate analysis and geostatistics were,applied to examine the sources and spatial distributions of heavy metals in soils; and the assessment on ecological risk of heavy metals was carried out using Hakanson's method. The average concentrations of 9 heavy metals were higher than the background values of Shandong Province; in particular, the mean contents of Cd, Hg, Pb and Zn were 2.42, 4.69, 1.74 and 1.54 times of their respective background values, which indicated there were obvious accumulations of these heavy metals in surface soils. The results from multivariate analysis suggested that all the 9 heavy metals could be classified as 3 Principal Components (PCs). Cd, Pb and Zn, having high loads in PC1, were dominated by industrial, agricultural and traffic sources. PC2 including Co, Cr and Ni came from natural sources, and were controlled by parent materials. As and Hg with high loads in PC3, were originated from coal combustion and smelting. Cu had some loads on different PCs, and was affected by both natural and human sources. Assessment on ecological risk indicated that the study area suffered from a critical level between high and moderate risks. Hg was at the high ecological risk level, and Cd was at the moderate ecological risk level, while other metals had low ecological risk level.

摘要

共采集了来自中国东部山东省典型工业城市莱芜市钢城区表层土壤的106个样本,测定了其中砷、镉、钴、铬、铜、汞、镍、铅和锌9种重金属的含量。运用多变量分析和地统计学方法研究土壤中重金属的来源和空间分布;采用哈坎森方法对重金属的生态风险进行评估。9种重金属的平均浓度均高于山东省背景值;特别是镉、汞、铅和锌的平均含量分别是各自背景值的2.42倍、4.69倍、1.74倍和1.54倍,表明这些重金属在表层土壤中存在明显积累。多变量分析结果表明,9种重金属可分为3个主成分(PCs)。镉、铅和锌在主成分1中载荷较高,主要来源于工业、农业和交通源。主成分2包括钴、铬和镍,来源于自然源,受母质控制。砷和汞在主成分3中载荷较高,源于煤炭燃烧和冶炼。铜在不同主成分上均有一定载荷,受自然和人为源共同影响。生态风险评估表明,研究区域处于高风险和中等风险之间的临界水平。汞处于高生态风险水平,镉处于中等生态风险水平,而其他金属处于低生态风险水平。

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