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基于溶质的拉格朗日方案在软物质溶液干燥过程建模中的应用

Solute based Lagrangian scheme in modeling the drying process of soft matter solutions.

作者信息

Meng Fanlong, Luo Ling, Doi Masao, Ouyang Zhongcan

机构信息

State Key Laboratory of Theoretical Physics, Institute of Theoretical Physics, Chinese Academy of Sciences, 100190, Beijing, China.

Kavli Institute for Theoretical Physics China, 100190, Beijing, China.

出版信息

Eur Phys J E Soft Matter. 2016 Feb;39(2):22. doi: 10.1140/epje/i2016-16022-9. Epub 2016 Feb 26.

DOI:10.1140/epje/i2016-16022-9
PMID:26920525
Abstract

We develop a new dynamical model to study the drying process of a droplet of soft matter solutions. The model includes the processes of solute diffusion, gel-layer formation and cavity creation. A new scheme is proposed to handle the diffusion dynamics taking place in such processes. In this scheme, the dynamics is described by the motion of material points taken on solute. It is convenient to apply this scheme to solve problems that involve moving boundaries and phase changes. As an example, we show results of a numerical calculation for a drying spherical droplet, and discuss how initial concentration and evaporation rate affect the structural evolution of the droplet.

摘要

我们开发了一个新的动力学模型来研究软物质溶液液滴的干燥过程。该模型包括溶质扩散、凝胶层形成和空洞产生的过程。提出了一种新的方案来处理这些过程中发生的扩散动力学。在该方案中,动力学由溶质上的物质点的运动来描述。将该方案应用于解决涉及移动边界和相变的问题很方便。作为一个例子,我们展示了干燥球形液滴的数值计算结果,并讨论了初始浓度和蒸发速率如何影响液滴的结构演变。

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本文引用的文献

1
Cavitation in drying droplets of soft matter solutions.软物质溶液干燥液滴中的空化现象。
Phys Rev Lett. 2014 Aug 29;113(9):098301. doi: 10.1103/PhysRevLett.113.098301. Epub 2014 Aug 25.
2
Shape, shell, and vacuole formation during the drying of a single concentrated whey protein droplet.单个浓缩乳清蛋白液滴干燥过程中的形状、外壳和液泡形成。
Langmuir. 2013 Dec 17;29(50):15606-13. doi: 10.1021/la404108v. Epub 2013 Dec 5.
3
Skin formation and bubble growth during drying process of polymer solution.聚合物溶液干燥过程中的皮肤形成与气泡生长
Eur Phys J E Soft Matter. 2012 Jul;35(7):57. doi: 10.1140/epje/i2012-12057-2. Epub 2012 Jul 11.
4
Onsager's variational principle in soft matter.昂萨格变分原理在软物质中的应用。
J Phys Condens Matter. 2011 Jul 20;23(28):284118. doi: 10.1088/0953-8984/23/28/284118. Epub 2011 Jun 27.
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Structure, dynamics, and rheology of colloid-polymer mixtures: from liquids to gels.胶体-聚合物混合物的结构、动力学及流变学:从液体到凝胶
J Chem Phys. 2009 Apr 7;130(13):134907. doi: 10.1063/1.3103889.
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Pharmaceutical particle engineering via spray drying.通过喷雾干燥进行药物颗粒工程
Pharm Res. 2008 May;25(5):999-1022. doi: 10.1007/s11095-007-9475-1. Epub 2007 Nov 28.
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Simple model of skin formation caused by solvent evaporation in polymer solutions.聚合物溶液中溶剂蒸发导致皮肤形成的简单模型。
Phys Rev Lett. 2006 Sep 29;97(13):136103. doi: 10.1103/PhysRevLett.97.136103. Epub 2006 Sep 26.
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Superficial wrinkles in stretched, drying gelatin films.
Langmuir. 2006 Apr 11;22(8):3622-6. doi: 10.1021/la052343m.
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Onset of buckling in drying droplets of colloidal suspensions.胶体悬浮液干燥液滴中的屈曲起始。
Phys Rev Lett. 2005 Jan 14;94(1):018302. doi: 10.1103/PhysRevLett.94.018302. Epub 2005 Jan 3.