Nakai Hidetaka, Matsuba Kengo, Akimoto Masataka, Nozaki Tomonori, Matsumoto Takahiro, Isobe Kiyoshi, Irie Masahiro, Ogo Seiji
Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan.
Department of Chemistry, Graduate School of Natural Science & Technology, Kanazawa University, Kakuma-machi, Kanazawa, 920-1192, Japan.
Chem Commun (Camb). 2016 Mar 21;52(23):4349-52. doi: 10.1039/c6cc00059b.
Rod-like millimetre-size crystals of a newly prepared rhodium dithionite complex with n-pentyl moieties bend upon photoirradiation and return to the initial shape upon heating; the roles of the flexible n-pentyl moieties as well as the photoreactive dithionite unit (μ-O2SSO2) are disclosed by single crystal X-ray diffraction.
一种新制备的带有正戊基部分的连二亚硫酸铑配合物的毫米级棒状晶体在光照射下会弯曲，并在加热时恢复到初始形状；单晶X射线衍射揭示了柔性正戊基部分以及光反应性连二亚硫酸根单元（μ-O₂SSO₂）的作用。
