Kajiwara Yuu, Miyata Seiya, Nakai Hidetaka
Department of Applied Chemistry, Faculty of Science and Engineering, Kindai University, 3-4-1 Kowakae, Higashi-Osaka 577-8502, Japan.
Dalton Trans. 2021 Dec 20;51(1):48-52. doi: 10.1039/d1dt03347f.
The crystalline-state photochromism of a new organorhodium dinuclear complex having -methoxypropyltetramethylcyclopentadienyl (η-CMe-CHOCH) and photoresponsive dithionite (μ-OSSO) ligands was investigated directly by performing single-crystal X-ray diffraction experiments; a reversible conformational change of the -methoxypropyl moiety was intriguingly observed during the course of a thermal back-reaction.
通过进行单晶X射线衍射实验，直接研究了一种具有 - 甲氧基丙基四甲基环戊二烯基（η-CMe-CHOCH）和光响应性连二亚硫酸根（μ-OSSO）配体的新型有机铑双核配合物的晶态光致变色现象；在热逆反应过程中，有趣地观察到了 - 甲氧基丙基部分的可逆构象变化。
