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秒级快速层层沉积法在柔性聚氨酯泡沫上制备阻燃涂层。

Ultra-Fast Layer-by-Layer Approach for Depositing Flame Retardant Coatings on Flexible PU Foams within Seconds.

机构信息

Dipartimento di Scienza Applicata e Tecnologia, Politecnico di Torino , Alessandria campus, Viale Teresa Michel 5, 15121 Alessandria, Italy.

Dipartimento di Chimica, Università degli Studi di Milano , Via Golgi 19, 20133 Milano, Italy.

出版信息

ACS Appl Mater Interfaces. 2016 Mar;8(10):6315-9. doi: 10.1021/acsami.6b00598. Epub 2016 Mar 3.

DOI:10.1021/acsami.6b00598
PMID:26925855
Abstract

In this letter, we are presenting a novel approach for the deposition of layer-by-layer (LbL) coatings capable of conferring flame retardant properties to flexible polyurethane foams exploiting subsecond deposition times. The process yields nanoscale coatings able to reduce by 33% one of the main fire safety parameters, namely the heat release rate peak, with a total treatment time of only 2.5 s. This new approach turned out to be three to 4 orders of magnitude faster than conventional LbL treatments. Such results make it possible for the exploit of LbL as a competitive, efficient and ecofriendly technology at industrial scale.

摘要

在这封信中,我们提出了一种新的方法,用于沉积层层(LbL)涂层,利用亚秒级的沉积时间为柔性聚氨酯泡沫赋予阻燃性能。该工艺可生成纳米级涂层,能够将主要消防安全参数之一的热释放率峰值降低 33%,总处理时间仅为 2.5 秒。这种新方法比传统的 LbL 处理快 3 到 4 个数量级。这些结果使得 LbL 能够在工业规模上作为一种具有竞争力、高效和环保的技术得到应用。

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