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新型瓜尔胶/Al2O3纳米复合材料作为孔雀石绿染料降解的有效光催化剂。

Novel guar gum/Al2O3 nanocomposite as an effective photocatalyst for the degradation of malachite green dye.

作者信息

Pathania Deepak, Katwal Rishu, Sharma Gaurav, Naushad Mu, Khan Mohammad Rizwan, Al-Muhtaseb Ala'a H

机构信息

School of Chemistry, Shoolini University, Solan, 173212 Himachal Pradesh, India.

School of Chemistry, Shoolini University, Solan, 173212 Himachal Pradesh, India.

出版信息

Int J Biol Macromol. 2016 Jun;87:366-74. doi: 10.1016/j.ijbiomac.2016.02.073. Epub 2016 Mar 2.

Abstract

Guar gum/Al2O3 (GG/AO) nanocomposite was prepared using simple and cost effective sol-gel method. This nanocomposite was characterized by several analytical techniques viz. scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), thermal analysis (TGA/DTA), Fourier transform infrared spectroscopy (FTIR) and ultraviolet-visible spectroscopy (UV-vis). The FTIR analysis confirmed that GG/AO composite material was formed. TEM images inferred the particle size in the range between 20 and 45nm. GG/AO nanocomposite exhibited good photocatalytic performance for malachite green (MG) dye (dye initial concentration 1.5×10(-5)M) degradation from aqueous phase. The adsorption followed by photocatalysis and coupled adsorption/photocatalysis reaction achieved about 80% and 90% degradation of MG dye under solar irradiation. Antibacterial test showed the excellent activity of GG/AO nanocomposite against Staphylococcus aureus.

摘要

采用简单且经济高效的溶胶-凝胶法制备了瓜尔胶/氧化铝(GG/AO)纳米复合材料。通过多种分析技术对该纳米复合材料进行了表征,即扫描电子显微镜(SEM)、透射电子显微镜(TEM)、X射线衍射(XRD)、热分析(TGA/DTA)、傅里叶变换红外光谱(FTIR)和紫外-可见光谱(UV-vis)。FTIR分析证实形成了GG/AO复合材料。TEM图像推断粒径在20至45nm之间。GG/AO纳米复合材料对水相中孔雀石绿(MG)染料(染料初始浓度为1.5×10⁻⁵M)的降解表现出良好的光催化性能。光催化吸附及耦合吸附/光催化反应在太阳辐射下实现了约80%和90%的MG染料降解。抗菌测试表明GG/AO纳米复合材料对金黄色葡萄球菌具有优异的活性。

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