Govinda Varadhi, Venkatesu Pannuru, Bahadur Indra
Department of Chemistry, University of Delhi, Delhi - 110 007, India.
Department of Chemistry and Material Science Innovation & Modelling (MaSIM) Research Focus Area, Faculty of Agriculture, Science and Technology, North-West University (Mafikeng Campus), Private Bag X2046, Mmabatho 2735, South Africa.
Phys Chem Chem Phys. 2016 Mar 28;18(12):8278-326. doi: 10.1039/c6cp00199h.
In view of the spacious scope of structural information and the molecular interactions between ammonium-based ionic liquids (ILs) and molecular solvents in various applications including chemical and pharmaceutical that are crucial for all aspects of scientific community, the knowledge of the molecular mechanisms, in particular, the thermodynamic basis of the structure-breaking/making interactions as well as the packing effect of the molecular liquids is essential to understand the ion-ion and ion-solvent interactions that exist in the liquid mixtures. In this perspective, we describe how the thermodynamic parameters can be effectively used to gain valuable insights into molecular interactions between ammonium-based ILs and molecular solvents, which would be most useful in various industries. This perspective presents the thermophysical properties of pure ammonium-based ILs, then these properties of the mixtures of these ILs with other solvents, and reviews the correlation researches on the properties of these systems. Finally, this perspective also brings a brief overview on several studies accomplished in this area by various researchers.
鉴于结构信息的广阔范围以及铵基离子液体（ILs）与分子溶剂之间的分子相互作用在包括化学和制药在内的各种应用中对科学界的各个方面都至关重要，了解分子机制，特别是结构破坏/形成相互作用的热力学基础以及分子液体的堆积效应，对于理解液体混合物中存在的离子-离子和离子-溶剂相互作用至关重要。从这个角度来看，我们描述了如何有效地利用热力学参数来深入了解铵基离子液体与分子溶剂之间的分子相互作用，这在各个行业中将非常有用。本视角介绍了纯铵基离子液体的热物理性质，然后是这些离子液体与其他溶剂混合物的这些性质，并综述了对这些体系性质的相关研究。最后，本视角还简要概述了不同研究人员在该领域完成的几项研究。
