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现场条件下用于可吸入结晶二氧化硅测量的高流速采样器性能:初步研究

Performance of High-Flow-Rate Samplers for Respirable Crystalline Silica Measurement Under Field Conditions: Preliminary Study.

作者信息

Coggins Marie A, Healy Catherine B, Lee Taekhee, Harper Martin

机构信息

School of Physics, National Univ. of Ireland, Galway, Ireland.

Exposure Assessment Branch, Health Effects Laboratory Division (HELD), National Institute for Occupational Safety and Health (NIOSH), Centers for Disease Control and Prevention (CDC), Morgantown, WV 26505, United States of America.

出版信息

Silica Assoc Respirable Miner Part (2012). 2014 Jan;STP 1565:125-138. doi: 10.1520/STP156520130141.

Abstract

UNLABELLED

Restoration stone work regularly involves work with high-silica-content materials (e.g., sandstone), but low-silica-content materials (<2 % quartz) such as limestone and lime mortar are also used. A combination of short sample duration and low silica content makes the quantification of worker exposure to respirable crystalline silica (RCS) difficult. This problem will be further compounded by the introduction of lower occupational exposure standards for RCS. The objective of this work was to determine whether higher-flow samplers might be an effective tool in characterizing lower RCS concentrations. A short study was performed to evaluate the performance of three high-flow samplers (FSP10, CIP10-R, and GK2.69) using side-by-side sampling with low-flow samplers (SIMPEDS and 10-mm nylon cyclones) for RCS exposure measurement at a restoration stonemasonry field site. A total of 19 side-by-side sample replicates for each high-flow and low-flow sampler pair were collected from work tasks involving limestone and sandstone.

RESULTS

Most of the RCS (quartz) masses collected with the high-flow-rate samplers were above the limit of detection (62 % to 84 %) relative to the low-flow-rate samplers (58 % to 78 %). The average of the respirable mass concentration ratios for CIP10-R/SIMPEDS, GK2.69/10-mm nylon, FSP10/SIMPEDS, and FSP10/10-mm nylon pairs and the range of the quartz concentration ratios for the CIP10-R/SIMPEDS, CIP10-R/10-mm nylon, GK2.69/10-mm nylon, FSP10/SIMPEDS, and FSP10/10-mm nylon pairs included unity with an average close to unity, indicating no likely difference between the reported values for each sampler. Workers reported problems related to the weight of the sampling pumps for the high-flow-rate samplers. Respirable mass concentration data suggest that the high-flow-rate samplers evaluated would be appropriate for sampling respirable dust concentrations during restoration stone work. Results from the comparison of average quartz concentration ratios between high-and low-flow samplers suggest that the higher mass collected by the high-flow-rate samplers did not interfere with the quartz measurement. A sig-nificant portion of the data collected with the high-flow-rate samplers (>82 %) were greater than the limit of detection, which indicates that these samplers are suitable for quantifying exposures, even with low-quartz materials.

摘要

未标注

修复石材工程经常涉及使用高硅含量材料(如砂岩),但也会使用低硅含量材料(石英含量<2%),如石灰石和石灰砂浆。采样时间短且硅含量低,使得量化工人接触可吸入结晶二氧化硅(RCS)的情况变得困难。RCS职业接触标准的降低会使这个问题进一步复杂化。这项工作的目的是确定高流量采样器是否可能是表征较低RCS浓度的有效工具。进行了一项简短研究,通过在一个修复石工现场与低流量采样器(SIMPEDS和10毫米尼龙旋风分离器)并排采样,评估三种高流量采样器(FSP10、CIP10-R和GK2.69)在测量RCS暴露方面的性能。从涉及石灰石和砂岩的工作任务中,为每个高流量和低流量采样器对总共收集了19组并排样本复制品。

结果

相对于低流量采样器(58%至78%),高流量采样器收集的大部分RCS(石英)质量高于检测限(62%至84%)。CIP10-R/SIMPEDS、GK2.69/10毫米尼龙、FSP10/SIMPEDS和FSP10/10毫米尼龙对的可吸入质量浓度比平均值以及CIP10-R/SIMPEDS、CIP10-R/10毫米尼龙、GK2.69/10毫米尼龙、FSP10/SIMPEDS和FSP10/10毫米尼龙对的石英浓度比范围包括1,且平均值接近1,表明每个采样器的报告值之间可能没有差异。工人报告了与高流量采样器的采样泵重量有关的问题。可吸入质量浓度数据表明,所评估的高流量采样器适用于在修复石材工程期间采样可吸入粉尘浓度。高流量和低流量采样器之间平均石英浓度比的比较结果表明,高流量采样器收集的较高质量不会干扰石英测量。高流量采样器收集的数据中很大一部分(>82%)大于检测限,这表明这些采样器即使对于低石英材料也适用于量化暴露。

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