Highly crystalline covalent organic frameworks from flexible building blocks.
作者信息
Xu Liqian, Ding San-Yuan, Liu Junmin, Sun Junliang, Wang Wei, Zheng Qi-Yu
机构信息
Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, China.
State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, Gansu 730000, China.
出版信息
Chem Commun (Camb). 2016 Mar 28;52(25):4706-9. doi: 10.1039/c6cc01171c.
Two novel 2D covalent organic frameworks (TPT-COF-1 and TPT-COF-2) were synthesized from the flexible 2,4,6-triaryloxy-1,3,5-triazine building blocks on a gram scale, which show high crystallinity and large surface area. The controllable formation of highly ordered frameworks is mainly attributed to the self-assembly Piedfort unit of 2,4,6-triaryloxy-1,3,5-triazine.
Zotero 插件