McCallum Monica E, Smith Genessa M, Matsumaru Takanori, Kong Ke, Enquist John A, Wood John L
Department of Chemistry and Biochemistry, Baylor University, Waco, TX, USA.
J Antibiot (Tokyo). 2016 Apr;69(4):331-6. doi: 10.1038/ja.2016.25. Epub 2016 Mar 9.
This manuscript describes the preparation of an advanced intermediate toward the total synthesis of citrinadin A, featuring a [3+2] cycloaddition employing in situ generation of the dipole.
本手稿描述了一种用于柑橘菌素A全合成的高级中间体的制备方法,其特点是采用偶极原位生成的[3+2]环加成反应。