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奶酪中受控消毒副产物的检测。

Detection of regulated disinfection by-products in cheeses.

作者信息

Cardador Maria Jose, Gallego Mercedes, Cabezas Lourdes, Fernández-Salguero Jose

机构信息

Department of Analytical Chemistry, Campus of Rabanales, University of Córdoba, E-14071 Córdoba, Spain.

Department of Analytical Chemistry, Campus of Rabanales, University of Córdoba, E-14071 Córdoba, Spain.

出版信息

Food Chem. 2016 Aug 1;204:306-313. doi: 10.1016/j.foodchem.2016.02.146. Epub 2016 Feb 26.

Abstract

Cheese can contain regulated disinfection by-products (DBPs), mainly through contact with brine solutions prepared in disinfected water or sanitisers used to clean all contact surfaces, such as processing equipment and tanks. This study has focused on the possible presence of up to 10 trihalomethanes (THMs) and 13 haloacetic acids (HAAs) in a wide range of European cheeses. The study shows that 2 THMs, (in particular trichloromethane) and 3 HAAs (in particular dichloroacetic acid) can be found at μg/kg levels in the 56 cheeses analysed. Of the two types of DBPs, HAAs were generally present at higher concentrations, due to their hydrophilic and non-volatile nature. Despite their different nature (THMs are lipophilic), both of them have an affinity for fatty cheeses, increasing their concentrations as the percentage of water decreased because the DBPs were concentrated in the aqueous phase of the cheeses.

摘要

奶酪可能含有受监管的消毒副产物(DBPs),主要是通过与在消毒水中制备的盐水溶液或用于清洁所有接触表面(如加工设备和罐体)的消毒剂接触。本研究聚焦于多种欧洲奶酪中可能存在的多达10种三卤甲烷(THMs)和13种卤乙酸(HAAs)。研究表明,在所分析的56种奶酪中,可以检测到μg/kg水平的2种THMs(特别是三氯甲烷)和3种HAAs(特别是二氯乙酸)。在这两种类型的DBPs中,HAAs通常以更高的浓度存在,这是由于它们的亲水性和非挥发性。尽管它们性质不同(THMs是亲脂性的),但它们都对高脂肪奶酪有亲和力,随着水分百分比的降低,它们的浓度会增加,因为DBPs集中在奶酪的水相中。

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