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丁酸催化升级制备精细化学品和生物燃料。

Catalytic upgrading of butyric acid towards fine chemicals and biofuels.

作者信息

Sjöblom Magnus, Matsakas Leonidas, Christakopoulos Paul, Rova Ulrika

机构信息

Biochemical Process Engineering, Division of Chemical Engineering, Department of Civil, Environmental and Natural Resources Engineering, Luleå University of Technology, SE-971 87 Luleå, Sweden

Biochemical Process Engineering, Division of Chemical Engineering, Department of Civil, Environmental and Natural Resources Engineering, Luleå University of Technology, SE-971 87 Luleå, Sweden.

出版信息

FEMS Microbiol Lett. 2016 Apr;363(8). doi: 10.1093/femsle/fnw064. Epub 2016 Mar 17.

Abstract

Fermentation-based production of butyric acid is robust and efficient. Modern catalytic technologies make it possible to convert butyric acid to important fine chemicals and biofuels. Here, current chemocatalytic and biocatalytic conversion methods are reviewed with a focus on upgrading butyric acid to 1-butanol or butyl-butyrate. Supported Ruthenium- and Platinum-based catalyst and lipase exhibit important activities which can pave the way for more sustainable process concepts for the production of green fuels and chemicals.

摘要

基于发酵生产丁酸的过程稳健且高效。现代催化技术使将丁酸转化为重要的精细化学品和生物燃料成为可能。在此,对当前的化学催化和生物催化转化方法进行综述,重点是将丁酸升级为1-丁醇或丁酸丁酯。负载型钌基和铂基催化剂以及脂肪酶表现出重要活性,可为生产绿色燃料和化学品的更可持续工艺概念铺平道路。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f5f0/4822402/7b888e3d4dd7/fnw064fig1.jpg

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