Noroozi Monir, Zakaria Azmi, Radiman Shahidan, Abdul Wahab Zaidan
Department of Physics, Faculty of Science, Universiti Putra Malaysia, Serdang, Selangor, Malaysia.
School of Applied Physics, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, Bangi, Selangor, Malaysia.
PLoS One. 2016 Apr 11;11(4):e0152699. doi: 10.1371/journal.pone.0152699. eCollection 2016.
In this paper, we report how few layers graphene that can be produced in large quantity with low defect ratio from exfoliation of graphite by using a high intensity probe sonication in water containing liquid hand soap and PVP. It was founded that the graphene powder obtained by this simple exfoliation method after the heat treatment had an excellent exfoliation into a single or layered graphene sheets. The UV-visible spectroscopy, FESEM, TEM, X-ray powder diffraction and Raman spectroscopy was used to analyse the graphene product. The thermal diffusivity of the samples was analysed using a highly accurate thermal-wave cavity photothermal technique. The data obtained showed excellent enhancement in the thermal diffusivity of the graphene dispersion. This well-dispersed graphene was then used to fabricate an electrically conductive polymer-graphene film composite. The results demonstrated that this low cost and environmental friendly technique allowed to the production of high quality layered graphene sheets, improved the thermal and electrical properties. This may find use in the wide range of applications based on graphene.
在本文中,我们报告了通过在含有洗手液和聚乙烯吡咯烷酮(PVP)的水中使用高强度探针超声处理从石墨剥离制备出的、可大量生产且缺陷率低的少层石墨烯。结果发现,通过这种简单剥离方法获得的石墨烯粉末在热处理后能很好地剥离成单层或多层石墨烯片。利用紫外可见光谱、场发射扫描电子显微镜(FESEM)、透射电子显微镜(TEM)、X射线粉末衍射和拉曼光谱对石墨烯产物进行了分析。使用高精度热波腔光热技术分析了样品的热扩散率。所得数据表明石墨烯分散体的热扩散率有显著提高。然后将这种分散良好的石墨烯用于制备导电聚合物 - 石墨烯薄膜复合材料。结果表明,这种低成本且环保的技术能够生产高质量的层状石墨烯片,改善了热性能和电性能。这可能在基于石墨烯的广泛应用中找到用武之地。