Cheng Fang, Leung Lydie, Wang Chen-Guang, Ji Wei, Polanyi John C
Lash Miller Chemical Laboratories, Department of Chemistry and Institute of Optical Sciences, University of Toronto, 80 St. George Street, Toronto, Ontario M5S 3H6, Canada.
Chem Commun (Camb). 2016 May 4;52(36):6115-8. doi: 10.1039/c6cc00849f. Epub 2016 Apr 13.
Two enantiomers were observed by Scanning Tunneling Microscopy (STM) when meta-iodopyridine was physisorbed on a 4.6 K Cu(110) surface. The chirality of the reagent was retained in the products of the electron-induced reaction. Dynamical calculations showed this to be a consequence of the reaction occurring on one side of the mirror plane.
当间碘吡啶物理吸附在4.6 K的Cu(110)表面时，通过扫描隧道显微镜（STM）观察到了两种对映体。该试剂的手性在电子诱导反应的产物中得以保留。动力学计算表明，这是反应在镜面一侧发生的结果。
