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通过紫外光固化粘合剂合成的银纳米线-碳纤维布纳米复合材料用于电化学现场水消毒。

Silver nanowire-carbon fiber cloth nanocomposites synthesized by UV curing adhesive for electrochemical point-of-use water disinfection.

作者信息

Hong Xuesen, Wen Junjie, Xiong Xuhua, Hu Yongyou

机构信息

The Key Lab of Pollution Control and Ecosystem Restoration in Industry Clusters, Ministry of Education, South China University of Technology, Guangzhou Higher Education Mega Centre, Guangzhou 510006, PR China; School of Civil Engineering and Transportation, South China University of Technology, Guangzhou 510640, PR China.

The Key Lab of Pollution Control and Ecosystem Restoration in Industry Clusters, Ministry of Education, South China University of Technology, Guangzhou Higher Education Mega Centre, Guangzhou 510006, PR China; School of Civil Engineering and Transportation, South China University of Technology, Guangzhou 510640, PR China.

出版信息

Chemosphere. 2016 Jul;154:537-545. doi: 10.1016/j.chemosphere.2016.04.013. Epub 2016 Apr 14.

Abstract

Novel silver nanowire (AgNW) - carbon fiber cloth (CC) nanocomposites were synthesized by a rapid and facile method. Acting as filter in an electrical gravity filtration device, the AgNW-CC nanocomposites were applied to electrochemical point-of-use water disinfection. AgNW-CC nanocomposites were characterized by FESEM, XRD, and FTIR. Their disinfection performance toward Escherichia coli and bacteriophage MS2 was evaluated by inhibition zone tests, optical density growth curve tests, and flow tests. The results showed that complex 3D AgNW networks with controllable silver release (<100 ppb) were fabricated on CC by using UV curing adhesive. AgNW-CC nanocomposites exhibited excellent intrinsic antibacterial activities against E. coli. The concentration of AgNWs and UV adhesive controlled the released silver and hence led to the change in antibacterial activity. The external electric field significantly enhanced the disinfection efficiency of AgNW-CC nanocomposites. Over 99.999% removal of E. coli and MS2 could be achieved. More complex AgNW networks contributed to higher disinfection efficiency under 10 V and 10(6) CFU (PFU) mL(-1) of microorganism. UV adhesive could keep the disinfection performance from being affected by flow rate. The convenient synthesis and outstanding disinfection performance offer AgNW-CC nanocomposites opportunities in the application of electrochemical point-of-use drinking water disinfection.

摘要

通过一种快速简便的方法合成了新型银纳米线(AgNW)-碳纤维布(CC)纳米复合材料。作为电动重力过滤装置中的过滤器,AgNW-CC纳米复合材料被应用于电化学现场水消毒。通过场发射扫描电子显微镜(FESEM)、X射线衍射(XRD)和傅里叶变换红外光谱(FTIR)对AgNW-CC纳米复合材料进行了表征。通过抑菌圈试验、光密度生长曲线试验和流动试验评估了它们对大肠杆菌和噬菌体MS2的消毒性能。结果表明,通过使用紫外线固化粘合剂在CC上制备了具有可控银释放(<100 ppb)的复杂三维AgNW网络。AgNW-CC纳米复合材料对大肠杆菌表现出优异的固有抗菌活性。AgNW的浓度和紫外线粘合剂控制了银的释放,从而导致抗菌活性的变化。外部电场显著提高了AgNW-CC纳米复合材料的消毒效率。对大肠杆菌和MS2的去除率可超过99.999%。在10 V电压和10(6) CFU(PFU)mL(-1) 的微生物浓度下,更复杂的AgNW网络有助于提高消毒效率。紫外线粘合剂可防止消毒性能受到流速的影响。这种简便的合成方法和出色的消毒性能为AgNW-CC纳米复合材料在电化学现场饮用水消毒中的应用提供了机会。

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