具有极高水稳定性的异金属类螺旋孔金属有机框架材料：通过掺杂金属离子调节孔隙率和疏水性
Exceptionally water stable heterometallic gyroidal MOFs: tuning the porosity and hydrophobicity by doping metal ions.
作者信息
Zhu Xiao-Wei, Zhou Xiao-Ping, Li Dan
机构信息
Department of Chemistry and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Guangdong 515063, P. R. China.
出版信息
Chem Commun (Camb). 2016 May 5;52(39):6513-6. doi: 10.1039/c6cc02116f.
PMID:27094095
Abstract
A strategy to improve the framework porosity and hydrophobicity of the pore surface by doping metal ions (Cu(2+), Cd(2+), or Fe(2+)) into a gyroidal MOF STU-1 has been developed. It is found that the obtained heterometallic MOFs are exceptionally water stable.
摘要
已开发出一种通过将金属离子（Cu(2+)、Cd(2+)或Fe(2+)）掺杂到类螺旋MOF STU-1中来改善框架孔隙率和孔表面疏水性的策略。研究发现，所获得的异金属MOF具有极高的水稳定性。
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