Xu Lin, Yang Hai-Bo
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, 3663 N. Zhongshan Road, Shanghai, 200062, P. R. China.
Chem Rec. 2016 Jun;16(3):1274-97. doi: 10.1002/tcr.201500271. Epub 2016 Apr 21.
During the past few decades, the construction of various kinds of platinum-acetylide complexes has attracted considerable attention, because of their wide applications in photovoltaic cells, non-linear optics, and bio-imaging materials. Among these platinum-acetylide complexes, the linear neutral platinum-acetylide complexes, due to their attractive properties, such as well-defined linear geometry, synthetic accessibility, and intriguing photoproperties, have emerged as a rising star in this field. In this personal account, we will discuss how we entered the field of linear neutral platinum-acetylide chemistry and what we found in this field. The preparation of various types of linear neutral platinum-acetylide complexes and their applications in the areas of micro/nanostructure materials, complicated topologies, and dye-sensitized solar cells will be summarized in this account.
在过去几十年里,各类铂乙炔配合物的构建引起了广泛关注,这是由于它们在光伏电池、非线性光学和生物成像材料等方面有着广泛应用。在这些铂乙炔配合物中,线性中性铂乙炔配合物因其具有吸引人的特性,如明确的线性几何结构、合成的可及性以及有趣的光性质,已成为该领域的一颗新星。在这篇个人综述中,我们将讨论我们是如何进入线性中性铂乙炔化学领域的,以及我们在该领域的发现。本文将总结各类线性中性铂乙炔配合物的制备及其在微/纳米结构材料、复杂拓扑结构和染料敏化太阳能电池等领域的应用。