Snβ沸石催化生物质衍生分子的氧化还原级联化学。

Snβ-zeolite catalyzed oxido-reduction cascade chemistry with biomass-derived molecules.

作者信息

Dijkmans J, Schutyser W, Dusselier M, Sels B F

机构信息

Center for Surface Chemistry and Catalysis, KU Leuven, Celestijnenlaan 200F, 3001 Heverlee, Belgium.

出版信息

Chem Commun (Camb). 2016 May 10;52(40):6712-5. doi: 10.1039/c6cc00199h.

DOI:10.1039/c6cc00199h

PMID:27117050

Abstract

High activity of post-synthetically synthesized Sn-beta, producing novel caprolactone polymer building blocks, is demonstrated in Meerwein-Ponndorf-Verley (MPV), Oppenauer (OPO), Baeyer-Villiger (BV) and cascade reactions thereof with biomass-derived molecules.

摘要

合成后制备的Sn-β具有高活性，可生成新型己内酯聚合物结构单元，这在Meerwein-Ponndorf-Verley（MPV）反应、奥本诺尔（OPO）反应、拜耳-维利格（BV）反应及其与生物质衍生分子的串联反应中得到了证实。