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高场固态核磁共振波谱研究(15)N 标记的玫瑰花状纳米管:氢键网络和通道束缚水。

High Field Solid-State NMR Spectroscopy Investigation of (15)N-Labeled Rosette Nanotubes: Hydrogen Bond Network and Channel-Bound Water.

机构信息

313 Snell Engineering Center, Northeastern University , 360 Huntington Avenue, Boston, Massachusetts 02115, United States.

Department of Chemistry, Redeemer University College , 777 Garner Road East, Ancaster, Ontario L9K 1J4, Canada.

出版信息

J Am Chem Soc. 2016 May 18;138(19):6115-8. doi: 10.1021/jacs.6b02420. Epub 2016 May 5.

DOI:10.1021/jacs.6b02420
PMID:27141817
Abstract

(15)N-labeled rosette nanotubes were synthesized and investigated using high-field solid-state NMR spectroscopy, X-ray diffraction, atomic force microscopy, and electron microscopy. The results established the H-bond network involved in the self-assembly of the nanostructure as well as bound water molecules in the nanotube's channel.

摘要

(15)N 标记的玫瑰花状纳米管通过高场固态 NMR 光谱学、X 射线衍射、原子力显微镜和电子显微镜进行了合成和研究。研究结果确定了参与纳米结构自组装的氢键网络以及纳米管通道中的结合水分子。

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