柔性极性离子在可变受限空间中的分子动力学：迈向卓越的两步非线性光学开关。
Molecular Dynamics of Flexible Polar Cations in a Variable Confined Space: Toward Exceptional Two-Step Nonlinear Optical Switches.
机构信息
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou, 510275, P. R. China.
Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, P. R. China.
出版信息
Adv Mater. 2016 Jul;28(28):5886-90. doi: 10.1002/adma.201600895. Epub 2016 May 9.
The changeable molecular dynamics of flexible polar cations in the variable confined space between inorganic chains brings about a new type of two-step nonlinear optical (NLO) switch with genuine "off-on-off" second harmonic generation (SHG) conversion between one NLO-active state and two NLO-inactive states.
柔性极性阳离子在无机链之间的可变受限空间中多变的分子动力学，带来了一种新型的两步非线性光学（NLO）开关，在一个 NLO 活性态和两个 NLO 非活性态之间具有真正的“关-开-关”二次谐波产生（SHG）转换。
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