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由小麦淀粉制备纳米多孔气凝胶。

Formation of nanoporous aerogels from wheat starch.

机构信息

Department of Food Science and Technology, University of Nebraska-Lincoln, Lincoln, NE 68588-6205, USA.

出版信息

Carbohydr Polym. 2016 Aug 20;147:125-132. doi: 10.1016/j.carbpol.2016.03.086. Epub 2016 Apr 1.

Abstract

Biodegradable nanoporous aerogels were obtained from wheat starch using a simple and green method based on supercritical carbon dioxide (SC-CO2) drying. Effects of processing parameters (temperature, wheat starch concentration and mixing rate during gelatinization; temperature, pressure, and flow rate of CO2, during SC-CO2 drying) on the aerogel formation were investigated, and optimized for the highest surface area and smallest pore size of the aerogels. At the optimized conditions, wheat starch aerogels had surface areas between 52.6-59.7m(2)/g and densities ranging between 0.05-0.29g/cm(3). The average pore size of the starch aerogels was 20nm. Starch aerogels were stable up to 280°C. Due to high surface area and nanoporous structure, wheat starch aerogels are promising carrier systems for bioactives and drugs in food and pharmaceutical industries.

摘要

采用基于超临界二氧化碳(SC-CO2)干燥的简单绿色方法,从小麦淀粉中获得可生物降解的纳米多孔气凝胶。研究了加工参数(在胶凝过程中的温度、小麦淀粉浓度和混合速率;在 SC-CO2 干燥过程中的温度、压力和 CO2 流量)对气凝胶形成的影响,并对其进行了优化,以获得气凝胶的最大比表面积和最小孔径。在优化条件下,小麦淀粉气凝胶的比表面积在 52.6-59.7m2/g 之间,密度在 0.05-0.29g/cm3 之间。淀粉气凝胶的平均孔径为 20nm。淀粉气凝胶在 280°C 下稳定。由于具有高的比表面积和纳米多孔结构,小麦淀粉气凝胶有望成为食品和制药行业中生物活性物质和药物的载体系统。

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