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纤维素-淀粉复合气凝胶作为超绝热材料

Cellulose-Starch Composite Aerogels as Thermal Superinsulating Materials.

作者信息

Ahmadzadeh Safoura, Sagardui Angelina, Huitink David, Chen Jingyi, Ubeyitogullari Ali

机构信息

Department of Food Science, University of Arkansas, Fayetteville, Arkansas 72704, United States.

Department of Chemical Engineering, University of Arkansas, Fayetteville, Arkansas 72701, United States.

出版信息

ACS Omega. 2024 Dec 2;9(50):49205-49213. doi: 10.1021/acsomega.4c05840. eCollection 2024 Dec 17.

DOI:10.1021/acsomega.4c05840
PMID:39713644
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11656253/
Abstract

The demand for sustainable packaging materials is rapidly increasing due to growing environmental concerns over the impact of plastic waste. In this study, biodegradable, porous, lightweight, and high-surface-area microcrystalline cellulose-starch (MCC-S) hybrid aerogels were synthesized via supercritical carbon dioxide (SC-CO) drying. The samples were generated using five different MCC-S weight ratios and characterized for their morphology, crystallinity, and structural and thermal properties. When MCC and S were used together, aerogels with superior properties were obtained compared to those made from each component individually. Specifically, the 1:2 MCC-S aerogel exhibited the highest porosity (97%), the lowest density (0.058 g/cm), and the lowest thermal conductivity (0.012 W/(m·K)) along with a high specific surface area (258 m/g). Therefore, MCC-S aerogels are promising insulators for advanced packaging applications, potentially serving as a sustainable alternative to Styrofoam.

摘要

由于对塑料垃圾影响的环境问题日益关注,对可持续包装材料的需求正在迅速增加。在本研究中,通过超临界二氧化碳(SC-CO)干燥合成了可生物降解、多孔、轻质且高比表面积的微晶纤维素-淀粉(MCC-S)混合气凝胶。使用五种不同的MCC-S重量比制备样品,并对其形态、结晶度以及结构和热性能进行表征。当MCC和S一起使用时,与单独由每种组分制成的气凝胶相比,获得了具有优异性能的气凝胶。具体而言,1:2的MCC-S气凝胶表现出最高的孔隙率(97%)、最低的密度(0.058 g/cm)和最低的热导率(0.012 W/(m·K))以及高比表面积(258 m/g)。因此,MCC-S气凝胶是用于先进包装应用的有前途的绝缘体,有可能作为聚苯乙烯泡沫塑料的可持续替代品。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/165c/11656253/bc30f6f365d1/ao4c05840_0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/165c/11656253/d02207710be4/ao4c05840_0001.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/165c/11656253/b61a02e319e4/ao4c05840_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/165c/11656253/2261f0e1b1dd/ao4c05840_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/165c/11656253/2925f47ed622/ao4c05840_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/165c/11656253/bc30f6f365d1/ao4c05840_0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/165c/11656253/d02207710be4/ao4c05840_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/165c/11656253/b4122e10483c/ao4c05840_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/165c/11656253/3f42272de56c/ao4c05840_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/165c/11656253/308682053b2c/ao4c05840_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/165c/11656253/b61a02e319e4/ao4c05840_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/165c/11656253/2261f0e1b1dd/ao4c05840_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/165c/11656253/2925f47ed622/ao4c05840_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/165c/11656253/bc30f6f365d1/ao4c05840_0008.jpg

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Enhancing the physicochemical properties and functional performance of starch-based films using inorganic carbon materials: A review.利用无机碳材料增强淀粉基薄膜的物理化学性能和功能特性:综述。
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