Key Laboratory of Eco-Textiles, Ministry of Education, College of Textile and Clothing, Jiangnan University, Wuxi, Jiangsu, 214122, China.
Key Laboratory of Eco-Textiles, Ministry of Education, College of Textile and Clothing, Jiangnan University, Wuxi, Jiangsu, 214122, China.
Int J Biol Macromol. 2016 Aug;89:614-21. doi: 10.1016/j.ijbiomac.2016.04.039. Epub 2016 May 11.
In this research, keratin was extracted from the disposable chicken feather using l-cysteine as reducing agent. Then, it was re-dissolved in the sodium carbonate-sodium bicarbonate buffer, and the pure keratin membrane and fiber were fabricated by doctor-blade casting process and wet spinning method, respectively. Scanning electron microscopy (SEM), fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD) and thermogravimetric analysis (TGA) were used to characterize the chemical and physical properties of resulting powder, membrane and fiber. Compared with the raw chicken feather, the regenerated keratin materials retain its chemical structure and thermal stability, their relative crystallinity is a little different depend on the shaping method, which leads to the difference in moisture regain. The mechanical results show that tensile strength of the keratin membrane researches 3.5MPa, have potential application in biomedical fields. However, the keratin fiber presents low tenacity, i.e. 0.5cN/dtex, this problem should be solved in order to apply the new fiber in textile and material science.
在这项研究中,使用 L-半胱氨酸作为还原剂从一次性鸡毛中提取角蛋白。然后,它在碳酸钠-碳酸氢钠缓冲液中重新溶解,并通过刮刀铸造工艺和湿法纺丝法分别制备纯角蛋白膜和纤维。扫描电子显微镜(SEM)、傅里叶变换红外(FT-IR)光谱、X 射线衍射(XRD)和热重分析(TGA)用于表征所得粉末、膜和纤维的化学和物理性质。与原始鸡毛相比,再生角蛋白材料保留了其化学结构和热稳定性,其相对结晶度因成型方法略有不同,这导致回潮率的差异。力学结果表明,角蛋白膜的拉伸强度为 3.5MPa,具有在生物医学领域的潜在应用。然而,角蛋白纤维的强度较低,即 0.5cN/dtex,为了将这种新型纤维应用于纺织和材料科学,这个问题需要解决。