Jin Mingoo, Seki Tomohiro, Ito Hajime
Division of Applied Chemistry and Frontier Chemistry Center, Faculty of Engineering, Hokkaido University, Sapporo, Hokkaido 060-8628, Japan.
Chem Commun (Camb). 2016 Jun 21;52(52):8083-6. doi: 10.1039/c6cc03541h.
Luminescent mechanochromism of a chiral gold(i) complex is investigated. The racemic and homochiral forms of the gold(i) complex possess distinct crystal packing arrangements with different emission colors. Upon mechanical stimulation, both crystals transform into amorphous powders that exhibit similar emission colors.
研究了一种手性金（I）配合物的发光机械变色现象。该金（I）配合物的外消旋体和纯手性形式具有不同的晶体堆积排列，发射颜色也不同。在机械刺激下，两种晶体都转变为具有相似发射颜色的无定形粉末。
