RIKEN Center for Emergent Matter Science, 2-1 Hirosawa, Wako, Saitama, 351-0198, Japan.
Graduate School of Advanced Integration Science, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba-shi, 263-8522, Japan.
Adv Mater. 2016 Aug;28(32):6921-5. doi: 10.1002/adma.201601373. Epub 2016 May 23.
A novel electron-deficient building unit, dithienylthienothiophenebisimide, and its polymers (PTBIs) are reported. Organic photovoltaic (OPV) cells based on PTBIs as p-type material exhibit 8.0% efficiencies with open-circuit voltages higher than 1 V. Interestingly, PTBIs also function as n-type material in OPVs depending on the molecular structure. These polymers also exhibit p-channel, n-channel, and ambipolar behaviors in field-effect transistors.
一种新型缺电子构筑单元二噻吩基噻吩并噻二酰亚胺及其聚合物(PTBIs)被报道。基于 PTBI 作为 p 型材料的有机光伏(OPV)器件表现出 8.0%的效率,开路电压高于 1V。有趣的是,PTBI 也可以根据分子结构在 OPV 中作为 n 型材料发挥作用。这些聚合物在场效应晶体管中也表现出 p 型、n 型和双极性行为。