Laboratory of Organic and Macromolecular Chemistry (IOMC), Friedrich Schiller University Jena, Humboldtstr. 10, 07743 Jena, Germany.
Chem Soc Rev. 2016 Oct 7;45(19):5311-57. doi: 10.1039/c6cs00182c. Epub 2016 May 24.
The incorporation of metal centers into the backbone of polymers has led to the development of a broad range of organometallic and coordination compounds featuring properties that are relevant for potential applications in diverse areas of research, ranging from energy storage/conversion to bioactive or self-healing materials. In this review, the basic concepts and synthetic strategies leading to these types of materials as well as the scope of available characterization techniques will be summarized and discussed.
将金属中心纳入聚合物的骨架中,导致了一系列有机金属和配位化合物的发展,这些化合物具有与储能/转换、生物活性或自修复材料等各个研究领域的潜在应用相关的特性。在这篇综述中,将总结和讨论导致这类材料的基本概念和合成策略,以及可用的表征技术的范围。