一种构建单环 1,4-氮杂硼烷的模块化合成方法。
A Modular Synthetic Approach to Monocyclic 1,4-Azaborines.
机构信息
Department of Chemistry, Boston College, Chestnut Hill, MA, 02467, USA.
College of Chemistry and Chemical Engineering, Tianjin University of Technology, China.
出版信息
Angew Chem Int Ed Engl. 2016 Jul 11;55(29):8333-7. doi: 10.1002/anie.201602840. Epub 2016 May 30.
PMID:27238094
Abstract
A simple and general method for the synthesis of a wide range of monocyclic 1,4-azaborines, including the first examples containing B heteroatoms is described. Post-heterocycle-formation olefin isomerization was employed as a key strategy. This new synthetic method provides fundamental insight into the resonance stabilization and photophysical properties of 1,4-azaborines.
摘要
本文描述了一种简单通用的合成广泛的单环 1,4-氮杂硼烷的方法，其中包括首例含有 B 杂原子的例子。后杂环形成的烯烃异构化被用作关键策略。这种新的合成方法为 1,4-氮杂硼烷的共振稳定和光物理性质提供了基本的认识。
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