Yang Kai, Zhang Guan, Song Qiuling
Institute of Next Generation Matter Transformation , College of Chemical Engineering , College of Material Sciences Engineering at Huaqiao University , 668 Jimei Boulevard , Xiamen , Fujian 361021 , P. R. China . Email:
State Key Laboratroy of Organometallic Chemistry , Shanghai Institute of Organic Chemistry , Chinese Academy of Sciences , Shanghai 200032 , P. R. China.
Chem Sci. 2018 Aug 13;9(39):7666-7672. doi: 10.1039/c8sc02281j. eCollection 2018 Oct 21.
To develop a simple and efficient synthetic method for four-coordinate triarylboranes, we herein describe a tandem highly selective B-Cl/C-B cross-metathesis of two of the same or different arylboranes and C-H bond borylation to synthesize four-coordinate triarylboranes with a broad substrate scope. By switching substituent groups of the target molecules, different emission wavelengths can be achieved from 467 nm to 583 nm with aggregation-induced emission (AIE) properties.
为了开发一种简单高效的四配位三芳基硼烷合成方法，我们在此描述了两种相同或不同芳基硼烷的串联高选择性B-Cl/C-B交叉复分解反应以及C-H键硼化反应，以合成具有广泛底物范围的四配位三芳基硼烷。通过切换目标分子的取代基，可以实现467纳米至583纳米的不同发射波长，并具有聚集诱导发光（AIE）特性。
Zotero 插件
