Department of Chemical and Biomolecular Engineering, Rice University , MS-362, 6200 Main Street, Houston, Texas 77005, United States.
Shell Global Solutions International , 2288GS Rijswijk, The Netherlands.
Langmuir. 2016 Jun 28;32(25):6239-45. doi: 10.1021/acs.langmuir.6b00949. Epub 2016 Jun 15.
We present the results of an experimental investigation of the effect of gas type and composition on foam transport in porous media. Steady-state foam strengths with respect to three cases of distinct gases and two cases containing binary mixtures of these gases were compared. The effects of gas solubility, the stability of lamellae, and the gas diffusion rate across the lamellae were examined. Our experimental results showed that the steady-state foam strength is inversely correlated with the gas permeability across a liquid lamella, a parameter that characterizes the rate of mass transport. The results are also in good agreement with existing observations that the foam strength for a mixture of gases is correlated with the less soluble component. Three hypotheses with different predictions of the underlying mechanism that explain the role of gas type and composition in foam strength are discussed in detail.
我们介绍了一项关于气体类型和组成对多孔介质中泡沫传输影响的实验研究结果。比较了三种不同气体和两种包含这些气体二元混合物的稳态泡沫强度。考察了气体溶解度、液膜稳定性和气体在液膜中扩散速率的影响。我们的实验结果表明,稳态泡沫强度与穿过液膜的气体渗透率成反比,渗透率是传质速率的特征参数。实验结果也与现有的观察结果一致,即气体混合物的泡沫强度与溶解度较低的组分有关。详细讨论了三种假说,这些假说对解释气体类型和组成在泡沫强度中的作用的潜在机制有不同的预测。