Center for Advancing Materials Performance from the Nanoscale & Hysitron Applied Research Center in China, State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University , Xi'an 710049, P.R. China.
Department of Mechanical Engineering and Bioengineering, Osaka University , Osaka 565-0871, Japan.
Nano Lett. 2016 Jul 13;16(7):4118-24. doi: 10.1021/acs.nanolett.6b00864. Epub 2016 Jun 6.
The workability and ductility of metals usually degrade with exposure to irradiation, hence the phrase "radiation damage". Here, we found that helium (He) radiation can actually enhance the room-temperature deformability of submicron-sized copper. In particular, Cu single crystals with diameter of 100-300 nm and containing numerous pressurized sub-10 nm He bubbles become stronger, more stable in plastic flow and ductile in tension, compared to fully dense samples of the same dimensions that tend to display plastic instability (strain bursts). The sub-10 nm He bubbles are seen to be dislocation sources as well as shearable obstacles, which promote dislocation storage and reduce dislocation mean free path, thus contributing to more homogeneous and stable plasticity. Failure happens abruptly only after significant bubble coalescence. The current findings can be explained in light of Weibull statistics of failure and the beneficial effects of bubbles on plasticity. These results shed light on plasticity and damage developments in metals and could open new avenues for making mechanically robust nano- and microstructures by ion beam processing and He bubble engineering.
金属的可加工性和延展性通常会随着辐照而降低,因此有了“辐射损伤”这一说法。在这里,我们发现氦(He)辐射实际上可以提高亚微米尺寸铜的室温变形能力。具体来说,与同样尺寸的完全致密样品相比,直径为 100-300nm 且含有大量加压亚 10nmHe 泡的 Cu 单晶在拉伸时具有更高的强度、更稳定的塑性流动和更好的延展性,而完全致密的样品往往会显示出塑性失稳(应变突发)。这些亚 10nmHe 泡既是位错源,也是可剪切的障碍物,它们促进位错存储并减小位错平均自由程,从而有助于实现更均匀和稳定的塑性。只有在大量气泡聚结后,才会突然发生失效。目前的发现可以用失效的威布尔统计和气泡对塑性的有益影响来解释。这些结果为金属的塑性和损伤发展提供了新的思路,并为通过离子束处理和 He 泡工程制造机械坚固的纳米和微结构开辟了新的途径。