Tsubonouchi Yuta, Lin Shu, Parent Alexander R, Brudvig Gary W, Sakai Ken
Department of Chemistry, Faculty of Sciences, Kyushu University, Motooka 744, Nishi-ku, Fukuoka 819-0395, Japan.
Chem Commun (Camb). 2016 Jun 28;52(51):8018-21. doi: 10.1039/c6cc02816k. Epub 2016 Jun 6.
A μ-oxido-bridged triruthenium complex (RuT(2+)), formed by air-oxidation of a previously reported monoruthenium water oxidation catalyst (WOC), serves as an efficient photochemical WOC with the turnover frequency (TOF) and turnover number (TON) 0.90 s(-1) and 610, respectively. The crystal structures of RuT(2+) and its one-electron oxidized RuT(3+) are also reported.
一种由先前报道的单钌水氧化催化剂（WOC）经空气氧化形成的μ-氧桥联三钌配合物（RuT(2+)），作为一种高效的光化学水氧化催化剂，其周转频率（TOF）和周转数（TON）分别为0.90 s(-1)和610。还报道了RuT(2+)及其单电子氧化产物RuT(3+)的晶体结构。
