过渡金属催化共轭烯炔合成的最新进展
Recent advances in transition-metal-catalyzed synthesis of conjugated enynes.
作者信息
Zhou Yujing, Zhang Yan, Wang Jianbo
机构信息
Beijing National Laboratory of Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China.
出版信息
Org Biomol Chem. 2016 Jul 12;14(28):6638-50. doi: 10.1039/c6ob00944a.
Conjugated enynes are of great importance in organic synthesis, biochemistry and materials sciences. The most commonly used synthetic methods include cross coupling reactions and dimerization reactions of alkynes. Despite many robust strategies being established, the improvement of reaction efficiency and development of novel transformations have still been actively pursued in the past decade. This review covers recent advances in transition-metal-catalyzed reactions in these fields.
共轭烯炔在有机合成、生物化学和材料科学中具有重要意义。最常用的合成方法包括炔烃的交叉偶联反应和二聚反应。尽管已经建立了许多成熟的策略，但在过去十年中，人们仍在积极寻求提高反应效率和开发新的转化方法。本综述涵盖了这些领域中过渡金属催化反应的最新进展。
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