Egbert Jonathan D, O'Hagan Molly, Wiedner Eric S, Bullock R Morris, Piro Nicholas A, Kassel W Scott, Mock Michael T
Center for Molecular Electrocatalysis, Pacific Northwest National Laboratory, P.O. Box 999, K2-57, Richland, WA 99352, USA.
Department of Chemistry, Villanova University, Villanova, PA, USA.
Chem Commun (Camb). 2016 Jul 19;52(60):9343-6. doi: 10.1039/c6cc03449g.
The first complete structurally and spectroscopically characterized series of isostructural Group 6 N2 complexes is reported. Protonolysis experiments on cis-[M(N2)2(P(Et)N(R)P(Et))2] (M = Cr, Mo, W; R = 2,6-difluorobenzyl) reveal that only Cr affords N2H5(+) and NH4(+) from the reduction of the N2 ligands.
报道了首个在结构和光谱方面得到完整表征的等结构第6族N₂配合物系列。对顺式-[M(N₂)₂(P(Et)N(R)P(Et))₂]（M = Cr、Mo、W；R = 2,6-二氟苄基）进行的质子解实验表明，只有Cr能通过还原N₂配体生成N₂H₅⁺和NH₄⁺。
