Zhang B, Zhang Y, Wang Z, Yang D, Gao Z, Wang D, Guo Y, Zhu D, Mori T
Organic Solid Laboratory, CMS & BNLMS, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. R. China.
Institute of Condensed Matter and Material Physics, School of Physics, Peking University, Beijing, 100871, P. R. China.
Dalton Trans. 2016 Oct 25;45(42):16561-16565. doi: 10.1039/c6dt01845a.
A radical cation salt composed of an organic donor, BEDT-TTF, and a one-dimensional inorganic anion, [Fe(CO)Cl], was obtained by electrocrystallization, and was identified as a semiconductor with values of σ = 3.0 × 10 S cm. Spin-canted antiferromagnetic long-range ordering was observed at 5.5 K from ZFCM/FCM/RM measurement and confirmed using AC measurement.
通过电结晶法获得了一种由有机供体BEDT-TTF和一维无机阴离子[Fe(CO)Cl]组成的自由基阳离子盐，经鉴定其为半导体，电导率σ = 3.0×10 S/cm。通过零场冷却/场冷却/剩余磁化强度测量在5.5 K观察到自旋倾斜反铁磁长程有序，并使用交流测量进行了确认。
