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（双（乙撑二硫）四硫富瓦烯）铜（甲酸）：一种有机-无机杂化导电磁体。

(BEDT-TTF)Cu(HCOO): An Organic-Inorganic Hybrid Conducting Magnet.

作者信息

Zhang Bin, Zhang Yan, Wang Zheming, Gao Zengqiang, Yang Deliang, Wang Dongwei, Guo Yanjun, Zhu Daoben

机构信息

Organic Solid Laboratory, CAS Research/Education Center for Excellence in Molecular Sciences, CMS & BNLMS, Institute of Chemistry Chinese Academy of Sciences Beijing 100190 P.R. China.

Institute of Condensed Matter and Material Physics, School of Physics Peking University Beijing 100871 P.R. China.

出版信息

ChemistryOpen. 2017 Apr 19;6(3):320-324. doi: 10.1002/open.201700041. eCollection 2017 Jun.

DOI:10.1002/open.201700041
PMID:28638760
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5474655/
Abstract

A dual-functional organic-inorganic hybrid (BEDT-TTF)Cu(HCOO) () (BEDT-TTF=bis(ethylenedithio)tetrathiafulvalene) was obtained through the electrochemical oxidation of neutral BEDT-TTF in the presence of an ammonium salt of the one-dimensional copper-formate framework [(CH)NH]Cu(HCOO) in a CHCl-CHOH solution. Compound  was composed of organic donor BEDT-TTF⋅ in a θ-phase arrangement and Jahn-Teller distorted (4,4) grid anion sheets [Cu(HCOO)] with 1/2. We identified the material as a semiconductor with values of =10 S cm. The anion sheet is a coordination isomer of [Cu(HCOO)] and, compared with the starting material, shows antiferromagnetic behavior as the well-known inorganic Cu-O, Co-O square layers for creating inorganic conducting magnets. Long-range antiferromagnetic ordering was observed at 8.0 K.

摘要

通过在CHCl-CHOH溶液中，在一维甲酸铜骨架[(CH)NH]Cu(HCOO)的铵盐存在下，对中性双(乙撑二硫)四硫富瓦烯（BEDT-TTF）进行电化学氧化，得到了一种双功能有机-无机杂化材料(BEDT-TTF)Cu(HCOO) （BEDT-TTF = 双(乙撑二硫)四硫富瓦烯）。化合物由处于θ相排列的有机供体BEDT-TTF⋅和具有1/2的Jahn-Teller畸变(4,4)网格阴离子片[Cu(HCOO)]组成。我们将该材料鉴定为一种半导体，其电导率值为10 S cm。阴离子片是[Cu(HCOO)] 的配位异构体，与起始材料相比，表现出反铁磁行为，就像众所周知的用于制造无机导电磁体的无机Cu-O、Co-O方形层一样。在8.0 K时观察到长程反铁磁有序。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c961/5474655/1522b16f7a72/OPEN-6-320-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c961/5474655/e14b40452ca0/OPEN-6-320-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c961/5474655/56fc2f4f7d17/OPEN-6-320-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c961/5474655/dfa1bd4b92bd/OPEN-6-320-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c961/5474655/1522b16f7a72/OPEN-6-320-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c961/5474655/e14b40452ca0/OPEN-6-320-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c961/5474655/56fc2f4f7d17/OPEN-6-320-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c961/5474655/dfa1bd4b92bd/OPEN-6-320-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c961/5474655/1522b16f7a72/OPEN-6-320-g004.jpg

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