利用氟原子对高热稳定性和光稳定性的近红外吸收七甲川花菁染料进行合理的分子设计与合成。
Rational Molecular Design and Synthesis of Highly Thermo- and Photostable Near-Infrared-Absorbing Heptamethine Cyanine Dyes with the Use of Fluorine Atoms.
作者信息
Funabiki Kazumasa, Yagi Kazutaka, Ueta Masato, Nakajima Mitsuru, Horiuchi Masako, Kubota Yasuhiro, Mastui Masaki
机构信息
Department of Chemistry and Biomolecular Science, Gifu University, 1-1 Yanagido, Gifu, Japan.
Yokkaichi Plant & Research Laboratories JSR Corporation, 100 Kawajiricho, Yokkaichi-shi, Mie, 510-8552, Japan.
出版信息
Chemistry. 2016 Aug 22;22(35):12282-5. doi: 10.1002/chem.201602955. Epub 2016 Jul 22.
Highly thermo- and photostable, near-infrared-absorbing heptamethine cyanine dyes were achieved with the use of fluorine-containing components. In particular, one prepared heptamethine cyanine dye, bearing a tetrakis(pentafluorophenyl)borate as a counter anion and an N-ethyl-2,2,2-trifluoroacetamido group at the meso position, showed not only a high decomposition temperature (Tdt ), but also very high photostability toward white LED irradiation.
通过使用含氟组分，获得了具有高热稳定性和光稳定性的近红外吸收七甲川花菁染料。特别地，制备的一种七甲川花菁染料，其带有四（五氟苯基）硼酸盐作为抗衡阴离子，并且在中位带有N-乙基-2,2,2-三氟乙酰胺基，不仅具有高分解温度（Tdt），而且对白色LED照射具有非常高的光稳定性。
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