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天然纳米材料的原位自组装:玻璃上绿色、简约且具有抗菌性能的碳纳米薄膜

Autochthonous self-assembly of nature's nanomaterials: green, parsimonious and antibacterial carbon nanofilms on glass.

作者信息

Gopal Judy, Muthu Manikandan, Chun Sechul

机构信息

Department of Bioresource and Food Science, Konkuk University, Seoul 143-701, Korea.

出版信息

Phys Chem Chem Phys. 2016 Jul 28;18(28):18670-7. doi: 10.1039/c6cp03478k. Epub 2016 Jun 29.

DOI:10.1039/c6cp03478k
PMID:27355696
Abstract

The development of thin film coatings has been a very important development in materials science for the modification of native material surface properties. Thin film coatings are enabled through the use of sophisticated instruments and technologies that demand expertise and huge initial and running costs. Nano-thin films are yet a furtherance of thin films which require more expertise and much more sophistication. In this work for the first time we present a one-pot straightforward carbon thin film coating methodology for glass substrates. There is novelty in every single aspect of the method, with the carbon used in the nanofilm being obtained from turmeric soot, the coating technique consisting of a basic immersion technique, a dip-dry method, in combination with the phytosoot-derived carbon's inherent ability to self-assemble to form a uniform and continuous stable coating. The carbon nanofilm has been characterized using field emission scanning electron microscopy (FESEM), Energy Dispersive X-ray (EDAX) analysis, a goniometer and X-ray diffraction (XRD). This study for the first time opens a new school of thought of using such naturally available free nanomaterials as eco-friendly green coatings. The amorphous porous carbon film can be coated on any hydrophilic substrate and is not substrate specific. Its added advantages of being transparent and antibacterial in spite of being green and parsimonious are meant to realize its utility as ideal choices for solar panels, medical implants and other construction applications.

摘要

薄膜涂层的发展是材料科学中一项非常重要的进展,用于改变天然材料的表面特性。薄膜涂层的实现需要使用复杂的仪器和技术,这需要专业知识以及高昂的初始成本和运行成本。纳米薄膜是薄膜的进一步发展,需要更多的专业知识和更高的复杂性。在这项工作中,我们首次提出了一种用于玻璃基板的一锅法直接碳薄膜涂覆方法。该方法的每个方面都具有新颖性,纳米薄膜中使用的碳来自姜黄烟灰,涂覆技术包括基本的浸渍技术、浸干法,以及植物烟灰衍生碳自组装形成均匀、连续稳定涂层的固有能力。已使用场发射扫描电子显微镜(FESEM)、能量色散X射线(EDAX)分析、测角仪和X射线衍射(XRD)对碳纳米薄膜进行了表征。这项研究首次开创了一种新的思路,即使用这种天然可得的免费纳米材料作为环保型绿色涂层。无定形多孔碳膜可以涂覆在任何亲水性基板上,不具有基板特异性。尽管它绿色且节俭,但具有透明和抗菌的额外优点,这意味着它有望成为太阳能电池板、医疗植入物和其他建筑应用的理想选择。

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