热和近红外光诱导的具有四硫富瓦烯稠合二吡啶并菲嗪配体的单核铁（II）配合物中的自旋交叉
Thermal and near-infrared light induced spin crossover in a mononuclear iron(ii) complex with a tetrathiafulvalene-fused dipyridophenazine ligand.
作者信息
Pointillart F, Liu X, Kepenekian M, Le Guennic B, Golhen S, Dorcet V, Roisnel T, Cador O, You Z, Hauser J, Decurtins S, Ouahab L, Liu S-X
机构信息
Institut des Sciences Chimiques de Rennes, UMR 6226 CNRS - Université de Rennes 1, 35042, Rennes Cedex, France.
出版信息
Dalton Trans. 2016 Jul 28;45(28):11267-71. doi: 10.1039/c6dt00920d. Epub 2016 Jun 30.
A mononuclear Fe(ii) complex involving a tetrathiafulvalene-based ligand exhibits thermal spin-crossover (around 143 K) with pronounced hysteresis behaviour (48 K). The chromophoric and π-extended ligand allows Near-Infrared (NIR) sensitization for the light-induced excited spin-state trapping (LIESST) with T(LIESST) = 90 K.
一种包含基于四硫富瓦烯配体的单核铁（II）配合物表现出热自旋交叉（约143 K），具有明显的滞后行为（48 K）。发色且具有π扩展的配体允许近红外（NIR）敏化，用于光诱导激发自旋态捕获（LIESST），其中T（LIESST）= 90 K。
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