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一种由锚定在碳层上的金属二硫化物纳米墙阵列组成的层状杂化体:原位杂交和改善的钠存储。

A Lamellar Hybrid Assembled from Metal Disulfide Nanowall Arrays Anchored on a Carbon Layer: In Situ Hybridization and Improved Sodium Storage.

机构信息

Key Laboratory of Materials for Energy Conversion, Chinese Academy of Sciences, Department of Materials Science and Engineering, University of Science and Technology of China, Hefei, 230026, Anhui, China.

Max Planck Institute for Solid State Research, Heisenbergstrasse 1, 70569, Stuttgart, Germany.

出版信息

Adv Mater. 2016 Sep;28(35):7774-82. doi: 10.1002/adma.201602009. Epub 2016 Jun 30.

Abstract

A lamellar hybrid assembled from metal disulfide (MoS2 , WS2 ) nanowall arrays anchored on nitrogen-doped carbon layers is developed via an in situ hybridization strategy through a synergistic pyrolysis reaction of thiourea and oxometalates. Such a hybrid provides adequate electrical and chemical coupling between the active materials and the carbon substrate, thus realizing a high-efficiency electron-conduction/ion-transportation system and exhibiting excellent sodium-storage properties.

摘要

通过硫脲和氧代金属盐的协同热解反应,采用原位杂化策略,开发了一种由锚定在氮掺杂碳层上的金属二硫化物(MoS2、WS2)纳米墙阵列组成的层状杂化材料。这种杂化材料在活性材料和碳基底之间提供了充分的电和化学耦合,从而实现了高效的电子传导/离子输运体系,并表现出优异的储钠性能。

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