• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

一种用于测量相平衡的小体积装置。

A Small-Volume Apparatus for the Measurement of Phase Equilibria.

作者信息

Outcalt Stephanie L, Lee Byung-Chul

机构信息

National Institute of Standards and Technology, Boulder, CO 80305-3328.

出版信息

J Res Natl Inst Stand Technol. 2004 Dec 1;109(6):525-31. doi: 10.6028/jres.109.039. Print 2004 Nov-Dec.

DOI:10.6028/jres.109.039
PMID:27366631
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC4856202/
Abstract

An apparatus has been designed and constructed for the measurement of vapor-liquid equilibrium properties. The main components of the apparatus consist of an equilibrium cell and a vapor circulation pump. The cell and all of the system valves are housed inside a temperature controlled, insulated aluminum block. The temperature range of the apparatus is 260 K to 380 K to pressures of 6 MPa. The uncertainty of the temperature measurement is 0.03 K, and the uncertainty in the pressure measurement is 9.8 × 10(-4) MPa. An automated data acquisition system is used to measure temperature and pressure at equilibrium. The apparatus has been performance tested by measuring the vapor pressures of propane, butane, and a standard mixture of propane + butane.

摘要

已设计并制造了一种用于测量气液平衡性质的装置。该装置的主要部件包括一个平衡池和一个蒸汽循环泵。平衡池和所有系统阀门都安装在一个温度可控的隔热铝块内。该装置的温度范围为260K至380K,压力可达6MPa。温度测量的不确定度为0.03K,压力测量的不确定度为9.8×10(-4)MPa。使用自动数据采集系统在平衡状态下测量温度和压力。该装置已通过测量丙烷、丁烷以及丙烷+丁烷标准混合物的蒸汽压进行了性能测试。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0c7/4856202/16bce3f74a36/j96outf4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0c7/4856202/f4eff3afe68b/j96outf1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0c7/4856202/a636b9ba02d3/j96outf2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0c7/4856202/2533c57c20f7/j96outf3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0c7/4856202/16bce3f74a36/j96outf4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0c7/4856202/f4eff3afe68b/j96outf1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0c7/4856202/a636b9ba02d3/j96outf2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0c7/4856202/2533c57c20f7/j96outf3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0c7/4856202/16bce3f74a36/j96outf4.jpg

相似文献

1
A Small-Volume Apparatus for the Measurement of Phase Equilibria.一种用于测量相平衡的小体积装置。
J Res Natl Inst Stand Technol. 2004 Dec 1;109(6):525-31. doi: 10.6028/jres.109.039. Print 2004 Nov-Dec.
2
Molecular Dynamics Simulations of the Vapor-Liquid Equilibria in CO/-Pentane, Propane/-Pentane, and Propane/-Hexane Binary Mixtures.CO/-戊烷、丙烷/-戊烷和丙烷/-己烷二元混合物中气液平衡的分子动力学模拟
J Phys Chem B. 2021 Jun 24;125(24):6658-6669. doi: 10.1021/acs.jpcb.1c03673. Epub 2021 Jun 14.
3
Thermoelectric temperature control device for vapor pressure measurements.用于蒸汽压力测量的热电温度控制装置。
Rev Sci Instrum. 2011 Aug;82(8):085110. doi: 10.1063/1.3628668.
4
Study on the phase behaviors, viscosities, and thermodynamic properties of CO2/[C(4)mim][PF(6)]/methanol system at elevated pressures.高压下CO2/[C(4)mim][PF(6)]/甲醇体系的相行为、粘度及热力学性质研究
Chemistry. 2003 Aug 18;9(16):3897-903. doi: 10.1002/chem.200204647.
5
Determination of vapor-liquid equilibrium data in microfluidic segmented flows at elevated pressures using Raman spectroscopy.采用拉曼光谱法在高压下测定微流分段流中的汽液平衡数据。
Anal Chem. 2015 Aug 18;87(16):8165-72. doi: 10.1021/acs.analchem.5b00699. Epub 2015 Jul 29.
6
Apparatus for Density and Dielectric Constant Measurements to 35 MPa on Fluids of Cryogenic Interest.用于在高达35兆帕压力下对低温相关流体进行密度和介电常数测量的装置。
J Res Natl Bur Stand (1977). 1983 Jul-Aug;88(4):241-252. doi: 10.6028/jres.088.012.
7
High-pressure phase equilibria with compressed gases.
Rev Sci Instrum. 2007 Dec;78(12):125104. doi: 10.1063/1.2814025.
8
Density measurements of subcooled water in the temperature range of (243 and 283) K and for pressures up to 400 MPa.在(243至283)K温度范围内以及高达400兆帕压力下对过冷水进行密度测量。
J Chem Phys. 2016 Feb 21;144(7):074501. doi: 10.1063/1.4941580.
9
Enzyme-catalyzed production of 1-glyceryl benzoate in compressed n-butane.在压缩正丁烷中酶催化生产苯甲酸-1-甘油酯。
Enzyme Microb Technol. 2010 May 5;46(6):513-9. doi: 10.1016/j.enzmictec.2010.01.007. Epub 2010 Feb 1.
10
Experimental and molecular modeling study of the three-phase behavior of (n-decane + carbon dioxide + water) at reservoir conditions.(正十二烷+二氧化碳+水)在油藏条件下的三相行为的实验和分子模拟研究。
J Phys Chem B. 2011 Dec 15;115(49):14591-609. doi: 10.1021/jp206806a. Epub 2011 Nov 14.

引用本文的文献

1
Bubble Point Measurements of Mixtures of HFO and HFC Refrigerants.氢氟烯烃(HFO)和氢氟碳化物(HFC)制冷剂混合物的泡点测量
J Chem Eng Data. 2021;66(12). doi: 10.1021/acs.jced.1c00654.
2
A Distillation Approach to Phase Equilibrium Measurements of Multicomponent Fluid Mixtures.一种用于多组分流体混合物相平衡测量的蒸馏方法。
Energy Fuels. 2019 Aug 15;33(8):7908-7915. doi: 10.1021/acs.energyfuels.9b01366. Epub 2019 Jun 25.
3
Bubble-Point Measurements and Modeling of Binary Mixtures of Linear Siloxanes.线性硅氧烷二元混合物的泡点测量与建模
J Chem Eng Data. 2018;63. doi: 10.1021/acs.jced.8b00200.
4
Bubble-Point Measurements of -Propane + -Decane Binary Mixtures with Comparisons of Binary Mixture Interaction Parameters for Linear Alkanes.丙烷 + 癸烷二元混合物的泡点测量以及线性烷烃二元混合物相互作用参数的比较
J Chem Eng Data. 2016 Jul 14;61(7):2573-2579. doi: 10.1021/acs.jced.6b00258. Epub 2016 Jul 1.