Lee Eunsoo, Thirupathaiah Bodakuntla, Han Jaeuk, Dahae Jung, Kim Choongik, Seo SungYong
J Nanosci Nanotechnol. 2016 Jan;16(1):910-9. doi: 10.1166/jnn.2016.10748.
New phenyl and phenylthienyl derivatives end-functionalized with carbazole and α-carboline, 9-(4- (9H-carbazol-9-yl)phenyl)-9H-carbazole, 9-(4-(9H-carbazol-9-yl)phenyl)-9H-pyrido[2,3-b]indole, 9-(3-(9H-carbazol-9-yl)phenyl)-9H-carbazole, 9-(3-(9H-carbazol-9-yl)phenyl)-9H-pyrido[2,3-b]indole, 9-(4-(5-(9H-carbazol-9-yl)thiophen-2-yl)phenyl)-9H-carbazole, and 9-(3-(5-(9H-carbazo-9-yl) thiophen-2-yl)phenyl)-9H-carbazole were synthesized and characterized as organic semiconductors for organic thin-film transistors (OTFTs). Most compounds exhibited p-channel characteristics with carrier mobility as high as 1.7 x 10⁻⁵ cm²/Vs and a current on/off ratio of 10²-10⁴ for top-contact/bottom-gate OTFT devices.
新的以咔唑和α-咔啉为端基官能化的苯基和苯并噻吩基衍生物、9-(4-(9H-咔唑-9-基)苯基)-9H-咔唑、9-(4-(9H-咔唑-9-基)苯基)-9H-吡啶并[2,3-b]吲哚、9-(3-(9H-咔唑-9-基)苯基)-9H-咔唑、9-(3-(9H-咔唑-9-基)苯基)-9H-吡啶并[2,3-b]吲哚、9-(4-(5-(9H-咔唑-9-基)噻吩-2-基)苯基)-9H-咔唑以及9-(3-(5-(9H-咔唑-9-基)噻吩-2-基)苯基)-9H-咔唑被合成并表征为用于有机薄膜晶体管(OTFT)的有机半导体。对于顶接触/底栅OTFT器件，大多数化合物表现出p沟道特性，载流子迁移率高达1.7×10⁻⁵ cm²/Vs，电流开/关比为10² - 10⁴ 。
