Solar System Exploration Division, NASA Goddard Space Flight Center , Greenbelt, Maryland 20771, United States.
Solar System Exploration Division, NASA Goddard Space Flight Center, Greenbelt, Maryland 20771, United States; Department of Chemistry, Catholic University, Washington, D.C. 20064, United States.
ACS Cent Sci. 2016 Jun 22;2(6):370-9. doi: 10.1021/acscentsci.6b00074. Epub 2016 Apr 25.
The analysis of amino acids in meteorites dates back over 50 years; however, it is only in recent years that research has expanded beyond investigations of a narrow set of meteorite groups (exemplified by the Murchison meteorite) into meteorites of other types and classes. These new studies have shown a wide diversity in the abundance and distribution of amino acids across carbonaceous chondrite groups, highlighting the role of parent body processes and composition in the creation, preservation, or alteration of amino acids. Although most chiral amino acids are racemic in meteorites, the enantiomeric distribution of some amino acids, particularly of the nonprotein amino acid isovaline, has also been shown to vary both within certain meteorites and across carbonaceous meteorite groups. Large l-enantiomeric excesses of some extraterrestrial protein amino acids (up to ∼60%) have also been observed in rare cases and point to nonbiological enantiomeric enrichment processes prior to the emergence of life. In this Outlook, we review these recent meteoritic analyses, focusing on variations in abundance, structural distributions, and enantiomeric distributions of amino acids and discussing possible explanations for these observations and the potential for future work.
对陨石中氨基酸的分析可以追溯到 50 多年前;然而,直到近年来,研究才从对少数陨石群(以默奇森陨石为例)的研究扩展到对其他类型和类别的陨石的研究。这些新的研究表明,在碳质球粒陨石群中,氨基酸的丰度和分布存在广泛的多样性,突出了母体过程和组成在氨基酸的产生、保存或改变中所起的作用。尽管大多数手性氨基酸在陨石中都是外消旋的,但一些氨基酸,特别是非蛋白质氨基酸异缬氨酸的对映体分布,也已经被证明在某些陨石内和碳质陨石群之间存在差异。在极少数情况下,还观察到一些外星蛋白质氨基酸的大 l-对映体过量(高达约 60%),这表明在生命出现之前存在非生物对映体富集过程。在这篇观点文章中,我们回顾了这些最近的陨石分析,重点讨论了氨基酸的丰度、结构分布和对映体分布的变化,并讨论了这些观察结果的可能解释以及未来工作的潜力。