Department of Earth and Planetray Sciences, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395, Japan.
Research Center for Planetary Trace Organic Compounds, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395, Japan.
Sci Rep. 2017 Apr 4;7(1):636. doi: 10.1038/s41598-017-00693-9.
The occurrence of extraterrestrial organic compounds is a key for understanding prebiotic organic synthesis in the universe. In particular, amino acids have been studied in carbonaceous meteorites for almost 50 years. Here we report ten new amino acids identified in the Murchison meteorite, including a new family of nine hydroxy amino acids. The discovery of mostly C and C structural isomers of hydroxy amino acids provides insight into the mechanisms of extraterrestrial synthesis of organic compounds. A complementary experiment suggests that these compounds could be produced from aldehydes and ammonia on the meteorite parent body. This study indicates that the meteoritic amino acids could be synthesized by mechanisms in addition to the Strecker reaction, which has been proposed to be the main synthetic pathway to produce amino acids.
外星有机化合物的出现是理解宇宙中前生物有机合成的关键。特别是,氨基酸在碳质陨石中已经被研究了近 50 年。在这里,我们报告了在默奇森陨石中鉴定出的十种新氨基酸,包括一个新的九种羟基氨基酸家族。羟基氨基酸的 C 和 C 结构异构体的发现为研究外星有机化合物合成的机制提供了线索。一项补充实验表明,这些化合物可以在母体陨石上由醛和氨生成。这项研究表明,陨石中的氨基酸可能是通过除斯特雷克反应以外的机制合成的,斯特雷克反应被认为是产生氨基酸的主要合成途径。