基于二维金属-有机骨架纳米片的金属硫化物纳米粒子的原位合成。
In Situ Synthesis of Metal Sulfide Nanoparticles Based on 2D Metal-Organic Framework Nanosheets.
机构信息
Center for Programmable Materials, School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore, 639798, Singapore.
Nanyang Environment and Water Research Institute, Interdisciplinary Graduate School, Nanyang Technological University, 50 Nanyang Avenue, Singapore, 639798, Singapore.
出版信息
Small. 2016 Sep;12(34):4669-74. doi: 10.1002/smll.201600976. Epub 2016 Jul 14.
A facile in situ synthetic method is developed to synthesize metal sulfide nanoparticles based on 2D M-TCPP (M = Cu, Cd, or Co, TCPP = tetrakis(4-carboxyphenyl)porphyrin)) metal-organic framework nanosheets. The obtained CuS/Cu-TCPP composite nanosheet is used as the active material in photoelectrochemical cells, showing notably increased photocurrent due to the improved exciton separation and charge carrier transport.
一种简便的原位合成方法被开发出来，用于合成基于二维 M-TCPP（M = Cu、Cd 或 Co，TCPP = 四(4-羧基苯基)卟啉)）金属-有机骨架纳米片的金属硫化物纳米粒子。所得的 CuS/Cu-TCPP 复合纳米片被用作光电化学电池中的活性材料，由于激子分离和电荷载流子输运的改善，表现出显著增加的光电流。
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